Quantitative infrared analysis of borophosphosilicate films using multivariate statistical methods

Journal Article · Wed Jun 01 00:00:00 EDT 1988 · Anal. Chem.; (United States)

DOI:https://doi.org/10.1021/ac00162a022· OSTI ID:6926306

Haaland, D M

Infrared (IR) spectroscopy can serve as a rapid method for the quantitative analysis of borophosphosilicate glass (BPSG) films on Si wafers for the microelectronics industry. The advantages of using statistically designed calibration sets are emphasized. Classical least-squares (CLS), partial least-squares (PLS), and principal component regression (PCR) methods are all found to provide improved precision over traditional peak-height measurements. The quantitative results from spectral measurements taken in transmission mode at both 0/sup 0/ and 60/sup 0/ incident angles were also compared. PLS and PCR methods yielded results that were comparable within the sampling error, and each exhibited a better analysis precision than that obtained from the CLS analysis. Both PLS and PCR methods yielded the best results when applied to the original 60/sup 0/ incident angle data, which was not corrected for film thickness. PLS and PCR analyses each gave a standard error of prediction (SEP) for boron of approx. = 0.1 wt% and approx. = 0.2 wt % for phosphorus for a set of 44 calibration samples which spanned a range of concentrations from 1 to 5 wt % B and 2 to 6 wt % P. The PLS and PCR methods applied to the IR spectra were also capable of monitoring film thickness with a SEP of 14 nm for films that varied in thickness from 430 to 1000 nm. The importance of using these full-spectrum multivariate methods for outlier sample detection is presented, and the ability to extract qualitative spectral information from the CLS and PLS calibrations is demonstrated.

• Research Organization: Sandia National Labs., Albuquerque, NM (USA)
• DOE Contract Number: AC04-76DP00789
• OSTI ID: 6926306
• Journal Information: Anal. Chem.; (United States), Journal Name: Anal. Chem.; (United States) Vol. 60:11; ISSN ANCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400102* -- Chemical & Spectral Procedures
BORON
BOROPHOSPHATE GLASS
BOROSILICATE GLASS
CALIBRATION
CHEMICAL ANALYSIS
DATA
ELEMENTS
EXPERIMENTAL DATA
FILMS
GLASS
INFORMATION
INFRARED SPECTRA
LEAST SQUARE FIT
MATHEMATICS
MAXIMUM-LIKELIHOOD FIT
MULTIVARIATE ANALYSIS
NONMETALS
NUMERICAL DATA
NUMERICAL SOLUTION
PHOSPHORUS
QUANTITATIVE CHEMICAL ANALYSIS
SEMIMETALS
SPECTRA
STATISTICS
THIN FILMS