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SGMA performance, design. Conclusion. Proper reservoir choice, fluid design keys to SGMA success

Journal Article · · Oil Gas J.; (United States)
OSTI ID:6920525
Self generating mud acid (SGMA) fluids are composed of an ammonium fluoride salt solution and an acid generating material such as methyl formate. Although several SGMA systems exist which can be used over the bottom-hole temperature range from 130/sup 0/ to 270/sup 0/F, the methyl formate type is the system reported on in this work. In this case, the methyl formate hydrolizes to formic acid and methyl alcohol at a rate which is dependent upon time and temperature. As the formic acid forms, it combines with the ammonium fluoride to produce hydrofluoric (HF) acid. Although HF acid concentrations up to about 3.5% by wt can be generated, the conventional system generates about 2%. The methyl formate system has been utilized mainly in a bottom-hole temperature range of from 130/sup 0/ to 190/sup 0/F. At reservoir temperatures below about 130/sup 0/F, HF generation becomes too slow for practical use. Also with this system, depending of course upon the pump rate, temperatures above 190/sup 0/F can cause a loss of in-depth HF capacity due to premature generation.
Research Organization:
Shell Oil Co
OSTI ID:
6920525
Journal Information:
Oil Gas J.; (United States), Journal Name: Oil Gas J.; (United States) Vol. 76:43; ISSN OIGJA
Country of Publication:
United States
Language:
English