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Comparison of multiple-photon excitation models

Journal Article · · Opt. Lett.; (United States)
DOI:https://doi.org/10.1364/OL.3.000152· OSTI ID:6919982

Two recent detailed models of multiple-photon excitation in SF/sub 6/ are compared. By performing equivalent vibration-rotation calculations using the two different basis sets, we have found that the results are in complete agreement. Rotational effects in both cases completely overshadow the vibrational structure, making a triply degenerate anharmonic oscillator model sufficient for describing multiple-photon excitation in SF/sub 6/.

Research Organization:
Theoretical Division, Los Alamos Scientific Laboratory, New Mexico 87545
OSTI ID:
6919982
Journal Information:
Opt. Lett.; (United States), Journal Name: Opt. Lett.; (United States) Vol. 3:4; ISSN OPLED
Country of Publication:
United States
Language:
English