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U.S. Department of Energy
Office of Scientific and Technical Information

Oil recovery by increasing the injectivity index of micellar systems containing crude oil sulfonates

Patent ·
OSTI ID:6910080
Flooding hydrocarbon-bearing, subterranean formations with micellar systems containing crude oil sulfonates is improved by extracting wax from the micellar system before it is injected into the formation. The extraction is effected with an agent consisting essentially of paraffinic hydrocarbons or halocarbons having a molecular weight of approx. 50 to 200. Aromatic extraction agents are not generally useful since they tend to be solubilized in the micellar system and, under certain conditions, have caused reduced oil recovery. Some aromatics can be tolerated, i.e., less than about 20% of the extraction agent. Extraction can be effected on the final micellar system, i.e., a micellar solution or microemulsion, before it is injected into the formation. The extraction also can be performed on the neutralized sulfonic acid stream from the sulfonation process simultaneously with removal of unsulfonated crude oil. The resulting micellar system can be subjected to slow cool-down rates or fast cool-down rates without adversely affecting injectivity of the system. 7 claims.
Assignee:
Marathon Oil Co.
Patent Number(s):
US 4147637
OSTI ID:
6910080
Country of Publication:
United States
Language:
English