Investigation of the alkaline dehydrochlorination of pentachloropropane. IV. Correlation between the structure and catalytic activity of salts of quaternary ammonium bases (QAB) in the alkaline dehydrochlorination of 1,1,2,2,3-pentachloropropane
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:6909459
The catalytic activity of 14 salts of QAB was investigated in the reaction of aqueous alkaline dehydrochlorination of 1,1,2,2,3 -pentachloropropane. A correlation equation relating the structure of the catalyst to its activity is derived. The values obtained for (..pi..R/sub 3/N/sup +/) /SUB max/ are compared with the value of (log P) /SUB max/ known from the literature, found in the investigation of the interaction of salts of QAB with biological substrates.
- OSTI ID:
- 6909459
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 26:6; ISSN KICAA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKANES
AMINES
AMMONIUM COMPOUNDS
BROMIDES
BROMINE COMPOUNDS
CATALYTIC EFFECTS
CHEMICAL COMPOSITION
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORIDES
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINE COMPOUNDS
CORRELATION FUNCTIONS
DECHLORINATION
DEHALOGENATION
FUNCTIONS
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
KINETICS
MATHEMATICAL MODELS
MOLECULAR STRUCTURE
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PROPANE
QUATERNARY COMPOUNDS
REACTION KINETICS
STRUCTURAL CHEMICAL ANALYSIS
400201* -- Chemical & Physicochemical Properties
ALKANES
AMINES
AMMONIUM COMPOUNDS
BROMIDES
BROMINE COMPOUNDS
CATALYTIC EFFECTS
CHEMICAL COMPOSITION
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORIDES
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINE COMPOUNDS
CORRELATION FUNCTIONS
DECHLORINATION
DEHALOGENATION
FUNCTIONS
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
KINETICS
MATHEMATICAL MODELS
MOLECULAR STRUCTURE
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PROPANE
QUATERNARY COMPOUNDS
REACTION KINETICS
STRUCTURAL CHEMICAL ANALYSIS