Reactions of O,S-diethyl (2-chloro-1-phenylvinyl)phosphonothioite with nitrilimines

Journal Article · Wed Dec 09 23:00:00 EST 1987 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6909181

Namestnikov, V I; Tamm, L A; Trishin, Yu G; Chistokletov, V N

The authors have found that for O,S-diethyl (2-chloro-1-phenylvinyl)phosphonothioite (3 + 3) cycloaddition to nitrilimines is also characteristic. The reactions go analogously to the reactions of diethyl (2-bromo-1-phenylvinyl)phosphonite with nitrilimines. As final products the authors obtained 4-(ethylthio)-1,4-dihydro-1,2,4-diazaphosphorine 4-oxides. The compositions and structures of the compounds were established on the basis of elemental analysis and IR, PMR, and /sup 31/P NMR spectroscopy.

• Research Organization: Leningrad Technological Institute of the Pulp and Paper Industry (USSR)
• OSTI ID: 6909181
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 57:6; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
AROMATICS
BENZENE
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORINATED ALIPHATIC HYDROCARBONS
CHLOROFORM
COUPLING
COUPLING CONSTANTS
DEUTERIUM COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
HYDROGEN COMPOUNDS
INFRARED SPECTRA
INTERMEDIATE COUPLING
ISOMERIZATION
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
SPECTRA
STABLE ISOTOPES