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Mechanisms limiting the performance of large grain polycrystalline silicon solar cells

Conference ·
OSTI ID:6907103

The open-circuit voltage and short-circuit current of large-grain (1 to 10 mm grain diameter) polycrystalline silicon solar cells is determined by the minority-carrier diffusion length within the bulk of the grains. This was demonstrated by irradiating polycrystalline and single-crystal (Czochralski) silicon solar cells with 1 MeV electrons to reduce their bulk lifetime. The variation of short-circuit current with minority-carrier diffusion length for the polycrystalline solar cells is identical to that of the single-crystal solar cells. The open-circuit voltage versus short-circuit current characteristic of the polycrystalline solar cells for reduced diffusion lengths is also identical to that of the single-crystal solar cell. The open-circuit voltage of the polycrystalline solar cells is a strong function of quasi-neutral (bulk) recombination, and is reduced only slightly, of at all, by grain-boundary recombination.

Research Organization:
Solarex Corp., Rockville, MD (USA); Jet Propulsion Lab., Pasadena, CA (USA); Cabot Corp., Billerica, MA (USA)
DOE Contract Number:
NAS-7-100-955902
OSTI ID:
6907103
Report Number(s):
CONF-831028-5; ON: DE84011688
Country of Publication:
United States
Language:
English