Vapor-liquid equilibrium of carbon dioxide in aqueous mixtures of monoethanolamine and methyldiethanolamine

Journal Article · Mon Aug 01 00:00:00 EDT 1994 · Industrial and Engineering Chemistry Research; (United States)

DOI:https://doi.org/10.1021/ie00032a016· OSTI ID:6905095

Jou, F Y; Otto, F D; Mather, A E ^[1]

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1. Univ. of Alberta, Edmonton (Canada). Dept. of Chemical Engineering

Aqueous solutions of alkanolamines are used to separate carbon dioxide and hydrogen sulfide from gas streams. Data for the distribution of carbon dioxide between the vapor and aqueous solutions of four mixtures of monoethanolamine (MEA) and methyldiethanolamine (MDEA) have been obtained at 25, 40, 80 and 120 C over a range of pressures from 100 kPa to 20 MPa. Partial pressures of CO[sub 2] ranged from 0.001 to 19,930 kPa. Enthalpies of reaction of CO[sub 2] in the solutions have been calculated from the solubility data.

• OSTI ID: 6905095
• Journal Information: Industrial and Engineering Chemistry Research; (United States), Journal Name: Industrial and Engineering Chemistry Research; (United States) Vol. 33:8; ISSN IECRED; ISSN 0888-5885
• Country of Publication: United States
• Language: English

Related Subjects

03 NATURAL GAS
030300* -- Natural Gas-- Drilling
Production
& Processing
AMINES
CARBON COMPOUNDS
CARBON DIOXIDE
CARBON OXIDES
CHALCOGENIDES
CLEANING
ENERGY SOURCES
ENTHALPY
FLUIDS
FOSSIL FUELS
FUEL GAS
FUELS
GAS FUELS
GASES
NATURAL GAS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
SOLUBILITY
SOLUTION HEAT
SOLVENT PROPERTIES
THERMODYNAMIC PROPERTIES