Electrochemical polymerization of 4-methyl-4 prime -vinyl-2,2 prime -bipyridine-containing metal complexes: Polymer structure and mechanism of formation
Journal Article
·
· Inorganic Chemistry; (USA)
- Colorado State Univ., Fort Collins (USA)
- Univ. of California, Riverside (USA)
The polymer structure and mechanism of formation of electroreductively polymerized 4-methyl-4{prime}-vinyl-2,2{prime}-bipyridine-containing metal complexes are described. Results from this large chromatography and laser desorption Fourier transform mass spectrometry demonstrate that normal polyvinyl-type chains are formed through chain propagation. For electrochemically polymerized poly-Fe(vbpy){sub 3}{sup 2+} an average chain length of seven repeat monomer units is determined. Separate copolymerization studies of mono- and tris(vinyl)-substituted complexes provide additional information on the nature of the polymerization process. 22 refs., 4 figs., 1 tab.
- OSTI ID:
- 6904391
- Journal Information:
- Inorganic Chemistry; (USA), Journal Name: Inorganic Chemistry; (USA) Vol. 29:3; ISSN 0020-1669; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
36 MATERIALS SCIENCE
360601* -- Other Materials-- Preparation & Manufacture
360602 -- Other Materials-- Structure & Phase Studies
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400400 -- Electrochemistry
AZINES
BIPYRIDINES
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
DATA
ELECTROCHEMISTRY
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
INFORMATION
IRON COMPLEXES
MOLECULAR STRUCTURE
MONOMERS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
POLYMERIZATION
PYRIDINES
RUTHENIUM COMPLEXES
TRANSITION ELEMENT COMPLEXES
VINYL MONOMERS
360601* -- Other Materials-- Preparation & Manufacture
360602 -- Other Materials-- Structure & Phase Studies
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400400 -- Electrochemistry
AZINES
BIPYRIDINES
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
DATA
ELECTROCHEMISTRY
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
INFORMATION
IRON COMPLEXES
MOLECULAR STRUCTURE
MONOMERS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
POLYMERIZATION
PYRIDINES
RUTHENIUM COMPLEXES
TRANSITION ELEMENT COMPLEXES
VINYL MONOMERS