Synthesis, characterization, and iodine doping of a soluble polyazine: The propyl methyl substituted derivative

Journal Article · · Chemistry of Materials; (USA)

DOI:https://doi.org/10.1021/cm00008a027· OSTI ID:6903577

Euler, W B ^[1]

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1. Univ. of Rhode Island, Kingston (USA)

Reaction of 2,3-hexanedione with 2,3-hexanedione dihydrazone leads to a polazine that is soluble in organic solvents. This synthetic method gives a polymer with statistically alternating methyl and propyl substituents on the carbon atoms along the chain. Like the previously reported permethyl polyazine, IR spectra suggest that the propyl methyl polymer is a linear chain with double bonds in the E conformation and single bonds in the anti (or s-trans) conformation. IR, UV-vis, and NMR spectra all imply that extensive conjugation exists along the polymer backbone.

• OSTI ID: 6903577
• Journal Information: Chemistry of Materials; (USA), Journal Name: Chemistry of Materials; (USA) Vol. 2:2; ISSN CMATE; ISSN 0897-4756
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360603* -- Materials-- Properties
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
DATA
DATA ANALYSIS
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
EXPERIMENTAL DATA
INFORMATION
INFRARED SPECTRA
MEASURING INSTRUMENTS
MEASURING METHODS
NUMERICAL DATA
ORGANIC COMPOUNDS
PHYSICAL PROPERTIES
POLYMERS
SPECTRA
SYNTHESIS