sup 113 Cd shielding tensors of the cadmium complex of texaphyrin, a novel expanded porphyrin, and its pyridine and benzimidazole adducts

Journal Article · Wed Mar 07 04:00:00 EST 1990 · Inorganic Chemistry; (USA)

DOI:https://doi.org/10.1021/ic00330a027· OSTI ID:6902254

Kennedy, M A; Ellis, P D ^[1]; Sessler, J L; Murai, Toshiaki ^[2]

---

1. Univ. of South Carolina, Columbia (USA)
2. Univ. of Texas, Austin (USA)

The cadmium complex of an expanded five-coordinate porphyrin known as texaphyrin and its complexes with pyridine and benzimidazole have been investigated by solution- and solid-state {sup 113}Cd NMR spectroscopy, and the results are reported. The principle shielding tensor elements were determined for each complex and are discussed in terms of reported crystal studies of Cd-texaphyrin and in comparison to cadmium complexes with other porphyrin and similar macrocycle ligands. 18 refs., 5 figs., 1 tab.

• OSTI ID: 6902254
• Journal Information: Inorganic Chemistry; (USA), Journal Name: Inorganic Chemistry; (USA) Vol. 29:5; ISSN 0020-1669; ISSN INOCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
ADDUCTS
AZINES
AZOLES
BENZIMIDAZOLES
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
CADMIUM 113
CADMIUM COMPLEXES
CADMIUM ISOTOPES
CARBOXYLIC ACIDS
COMPLEXES
DATA
EVEN-ODD NUCLEI
EXPERIMENTAL DATA
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
IMIDAZOLES
INFORMATION
INTERMEDIATE MASS NUCLEI
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
NMR SPECTRA
NUCLEI
NUMERICAL DATA
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
POLYMERS
PORPHYRINS
PYRIDINE
PYRIDINES
RADIOISOTOPES
SPECTRA
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
YEARS LIVING RADIOISOTOPES