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Title: Ion beam synthesis of IrSi[sub 3] by implantation of 2 MeV Ir ions

Conference ·
OSTI ID:6901805
;  [1];  [2]
  1. Oak Ridge National Lab., TN (United States)
  2. Forschungszentrum Juelich, Juelich (Germany)

Formation of a buried IrSi[sub 3] layer in (111) oriented Si by ion implantation and annealing has been studied at an implantation energy of 2 MeV for substrate temperatures of 450--550C. Rutherford backscattering (RBS), ion channeling and cross-sectional transmission electron microscopy showed that a buried epitaxial IrSi[sub 3] layer is produced at 550C by implanting [ge] 3.4 [times] 10[sup 17] Ir/cm[sup 2] and subsequently annealing for 1 h at 1000C plus 5 h at 1100C. At a dose of 3.4 [times] 10[sup 17] Ir/cm[sup 2], the thickness of the layer varied between 120 and 190 nm and many large IrSi[sub 3] precipitates were present above and below the film. Increasing the dose to 4.4 [times] 10[sup 17] Ir/cm[sup 2] improved the layer uniformity at the expense of increased lattice damage in the overlying Si. RBS analysis of layer formation as a function of substrate temperature revealed the competition between the mechanisms for optimizing surface crystallinity vs. IrSi[sub 3] layer formation. Little apparent substrate temperature dependence was evident in the as-implanted state but after annealing the crystallinity of the top Si layer was observed to deteriorate with increasing substrate temperature while the precipitate coarsening and coalescence improved.

Research Organization:
Oak Ridge National Lab., TN (United States)
Sponsoring Organization:
USDOE; USDOE, Washington, DC (United States)
DOE Contract Number:
AC05-84OR21400
OSTI ID:
6901805
Report Number(s):
CONF-921101-32; ON: DE93005755
Resource Relation:
Conference: 16. Material Research Society international symposium on the scientific basis for nuclear waste management fall meeting, Boston, MA (United States), 30 Nov - 5 Dec 1992
Country of Publication:
United States
Language:
English