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Pegmatite-wallrock interaction: holmquistite-bearing amphibolite, Edison pegmatite, Black Hills, South Dakota

Journal Article · · Am. Mineral.; (United States)
OSTI ID:6894581
The fluid transport of relatively incompatible elements (Li, Rb, Cs) out of the rare-element pegmatite system and the subsequent interaction between that fluid and amphibolite result in the stabilization of holmquistite-bearing assemblages. In the amphibolite adjacent to the Edison pegmatite, Black Hills, South Dakota, three amphibolite assemblages resulting from fluid-country rock interaction can be distinguished: (1) biotite alteration assemblage, (2) hornblende-holmquistite alteration assemblage, and (3) hornblende-plagioclase assemblage. Holmquistite occurs only in assemblages 1 and 2 in which it coexists with and partially replaces hornblende. In coexisting holmquistite-hornblende pairs, the (Al + Fe/sup 3 +/ + 2Ti/sup 4 +/) value is greater, and the (Fe/sup 2 +/ + Mn)/(Fe/sup 2 +/ + Mn + Mg) ratio is less in holmquistite than in coexisting hornblende. By analogy to calcic and Fe-Mg amphiboles, a wide compositional gap exists between calcic and Li-rich amphiboles at temperatures of alteration-zone formation. The alteration of the amphibolite appears to be the result of (1) Li and K metasomatic alteration by alkali-rich, pegmatite-derived aqueous fluids and (2) retrograde metamorphism by the aqueous fluids resulting in the instability of plagioclase and ilmenite and the formation of epidote and sphene. The fluid has low B and F concentrations relative to fluids derived from lepidolite-bearing pegmatites in the same region. The conditions at which the alteration occurred were between 510 and 350/sup 0/C at 3-4 kbar. Field and textural evidence cannot discriminate between a single fluid-amphibolite interaction model and a multiple fluid-amphibolite interaction model. 51 references.
Research Organization:
South Dakota School of Mines and Technology, Rapid City (USA)
DOE Contract Number:
FG01-84ER13259
OSTI ID:
6894581
Journal Information:
Am. Mineral.; (United States), Journal Name: Am. Mineral.; (United States) Vol. 73:3-4; ISSN AMMIA
Country of Publication:
United States
Language:
English