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An experimental study and a thermodynamic evaluation of the Fe-Cr-Mo system

Journal Article · · Metall. Trans., A; (United States)
DOI:https://doi.org/10.1007/BF02674012· OSTI ID:6887588
An experimental study of the Fe-Cr-Mo system has been made using a diffusion couple technique. Both ends of a large number of tie-lines have been determined using both an electron microprobe and a scanning electron microscope with energy dispersive X-ray analysis equipment. The isothermal sections at 1223, 1273, 1373, and 1473 K have been constructed from the experimental data and thermodynamic model calculations. The Gibbs energy of the intermetallic phases has been described with a recently developed model for phases with several sublattices. The parameter values describing the Gibbs energy of each individual phase were determined with a computerized optimization technique. The calculated phase diagrams are in satisfactory agreement with the experimental information and allow reasonable extrapolation outside the experimental temperature range.
Research Organization:
National Bureau of Standards, Gaithersburg, MD (US)
OSTI ID:
6887588
Journal Information:
Metall. Trans., A; (United States), Journal Name: Metall. Trans., A; (United States) Vol. 19A:6; ISSN MTTAB
Country of Publication:
United States
Language:
English