Thermal and light-induced reduction of (+)-tris(bipyridyl)ruthenium(III) in aqueous solution: mechanistic inferences from optical rotation studies
Journal Article
·
· Inorg. Chem.; (United States)
The thermal (pH 6.5) and light-induced (pH 2) reduction of (+)-Ru(bpy)/sub 3//sup 3 +/ (bpy = 2,2'-bipyridine) in aqueous solution proceeds with complete retention of optical activity. The present results, together with previous data on the stoichiometry and kinetics of these reactions, lend strong support to Creutz and Sutin's postulate of pseudobase structure for the hydroxyl ion containing Ru(III) intermediate. 19 references, 1 table.
- Research Organization:
- Alchemie Research Centre, Maharashtra, India
- OSTI ID:
- 6882448
- Journal Information:
- Inorg. Chem.; (United States), Vol. 25:24
- Country of Publication:
- United States
- Language:
- English
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Photocatalytic reduction of phenacyl halides by 9,10-dihydro-10-methylacridine. Control between the reductive and oxidative quenching pathways of tris(bipyridine)ruthenium complex utilizing an acid catalysis
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Related Subjects
14 SOLAR ENERGY
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BIPYRIDINES
PHOTOCHEMISTRY
REDUCTION
ORGANOMETALLIC COMPOUNDS
RUTHENIUM COMPLEXES
TEMPERATURE EFFECTS
AZINES
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
HETEROCYCLIC COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PYRIDINES
TRANSITION ELEMENT COMPLEXES
140505* - Solar Energy Conversion- Photochemical
Photobiological
& Thermochemical Conversion- (1980-)
400500 - Photochemistry
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BIPYRIDINES
PHOTOCHEMISTRY
REDUCTION
ORGANOMETALLIC COMPOUNDS
RUTHENIUM COMPLEXES
TEMPERATURE EFFECTS
AZINES
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
HETEROCYCLIC COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PYRIDINES
TRANSITION ELEMENT COMPLEXES
140505* - Solar Energy Conversion- Photochemical
Photobiological
& Thermochemical Conversion- (1980-)
400500 - Photochemistry