Thermal and light-induced reduction of (+)-tris(bipyridyl)ruthenium(III) in aqueous solution: mechanistic inferences from optical rotation studies
Journal Article
·
· Inorg. Chem.; (United States)
The thermal (pH 6.5) and light-induced (pH 2) reduction of (+)-Ru(bpy)/sub 3//sup 3 +/ (bpy = 2,2'-bipyridine) in aqueous solution proceeds with complete retention of optical activity. The present results, together with previous data on the stoichiometry and kinetics of these reactions, lend strong support to Creutz and Sutin's postulate of pseudobase structure for the hydroxyl ion containing Ru(III) intermediate. 19 references, 1 table.
- Research Organization:
- Alchemie Research Centre, Maharashtra, India
- OSTI ID:
- 6882448
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 25:24; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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OSTI ID:6861614
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· J. Phys. Chem.; (United States)
·
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Related Subjects
14 SOLAR ENERGY
140505* -- Solar Energy Conversion-- Photochemical
Photobiological
& Thermochemical Conversion-- (1980-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500 -- Photochemistry
AZINES
BIPYRIDINES
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
HETEROCYCLIC COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHOTOCHEMISTRY
PYRIDINES
REDUCTION
RUTHENIUM COMPLEXES
TEMPERATURE EFFECTS
TRANSITION ELEMENT COMPLEXES
140505* -- Solar Energy Conversion-- Photochemical
Photobiological
& Thermochemical Conversion-- (1980-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500 -- Photochemistry
AZINES
BIPYRIDINES
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
HETEROCYCLIC COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHOTOCHEMISTRY
PYRIDINES
REDUCTION
RUTHENIUM COMPLEXES
TEMPERATURE EFFECTS
TRANSITION ELEMENT COMPLEXES