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Title: Measurement of infrared absorption of some oxides in connection with the radiative transfer in porous and fibrous materials

Journal Article · · Int. J. Thermophys.; (United States)
DOI:https://doi.org/10.1007/BF00503227· OSTI ID:6878028

It is shown in the case of Al/sub 2/O/sub 3/ and MgO that the analysis of absorption data as a function of temperature gives the possibility of decomposing the lattice absorption coefficient in its different multiphonon contributions. Measurements performed on TiO/sub 2/ and ZrO/sub 2/ also are reported; it is observed that electronic effects considerably enhance the absorption level at high temperatures. From diffuse reflection measurements on a scattering sample, the ratio of absorption and scattering can be obtained. So experimental data can be used to calculate the radiant flux. Several models have been proposed, based on isotropic and anisotropic approximations. They involve the absorption coefficient sigma/sub a/, the scattering coefficient sigma/sub s/, the backscattered fraction factor b, and a phase function parameter a/sub 1/. Due to the approximations on which the models are based, the calculated values of the radiant heat flux show large differences (as large as 30%), whatever the accuracy of the values of optical parameters which are used. It appears worthy to use the experimental data on sigma/sub a/ and sigma/sub s/, which can be obtained from transmission and diffuse reflection measurements.

Research Organization:
Universite d'Orleans, France
OSTI ID:
6878028
Journal Information:
Int. J. Thermophys.; (United States), Vol. 8:1
Country of Publication:
United States
Language:
English

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