Synthesis and characterization of oxide interstitial derivatives of zirconium monochloride and monobromide
Technical Report
·
OSTI ID:6877544
An investigation into the reactivity of ZrX (X = Br,Cl) found no evidence for successful intercalation of ZrCl between the chloride layers with NH/sub 3/, pyridine, CO, n-butyl lithium, Li/NH/sub 3/, K/NH/sub 3/, and Li; and Zr plus LiCl, CsCl, and NaCl. Reactions of ZrX + n ZrO/sub 2/ at 850 to 1000/sup 0/ for two weeks produced an expanded ZrX structure (ZrX(O/sub y)) and the metal phase Zr(O/sub x/)(X/sub p/) (p congruent to 0). Three ZrCl(O/sub y/) crystal structures were refined.
- Research Organization:
- Ames Lab., IA (USA)
- DOE Contract Number:
- W-7405-ENG-82
- OSTI ID:
- 6877544
- Report Number(s):
- IS-T-1036; ON: DE83004861
- Country of Publication:
- United States
- Language:
- English
Similar Records
Synthesis and characterization of oxide interstitial derivatives of zirconium monochloride and monobromide
Synthesis by hydrogen-driven disproportionation reactions. Synthesis and structure of the hexazirconium dodecahalide clusters Zr/sub 6/Cl/sub 12/ and Zr/sub 6/Br/sub 12/ and the double salt Zr/sub 6/Cl/sub 12/. M/sub 2/ZrCl/sub 6/(M = Na, K, Cs)
Intercalation and interstitial derivatives of yttrium monochloride
Journal Article
·
Wed Oct 26 00:00:00 EDT 1983
· Inorg. Chem.; (United States)
·
OSTI ID:5596895
Synthesis by hydrogen-driven disproportionation reactions. Synthesis and structure of the hexazirconium dodecahalide clusters Zr/sub 6/Cl/sub 12/ and Zr/sub 6/Br/sub 12/ and the double salt Zr/sub 6/Cl/sub 12/. M/sub 2/ZrCl/sub 6/(M = Na, K, Cs)
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Wed Dec 31 23:00:00 EST 1980
· Inorg. Chem.; (United States)
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OSTI ID:6607460
Intercalation and interstitial derivatives of yttrium monochloride
Technical Report
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Sat Dec 31 23:00:00 EST 1983
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OSTI ID:5340728
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AMMONIA
AZINES
BROMIDES
BROMINE COMPOUNDS
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
CLATHRATES
CRYSTAL STRUCTURE
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
HYDRIDES
HYDROGEN COMPOUNDS
LATTICE PARAMETERS
NITROGEN COMPOUNDS
NITROGEN HYDRIDES
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDATION
OXIDES
OXYGEN COMPOUNDS
PYRIDINE
PYRIDINES
TRANSITION ELEMENT COMPOUNDS
ZIRCONIUM BROMIDES
ZIRCONIUM CHLORIDES
ZIRCONIUM COMPOUNDS
ZIRCONIUM OXIDES
400201* -- Chemical & Physicochemical Properties
AMMONIA
AZINES
BROMIDES
BROMINE COMPOUNDS
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
CLATHRATES
CRYSTAL STRUCTURE
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
HYDRIDES
HYDROGEN COMPOUNDS
LATTICE PARAMETERS
NITROGEN COMPOUNDS
NITROGEN HYDRIDES
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDATION
OXIDES
OXYGEN COMPOUNDS
PYRIDINE
PYRIDINES
TRANSITION ELEMENT COMPOUNDS
ZIRCONIUM BROMIDES
ZIRCONIUM CHLORIDES
ZIRCONIUM COMPOUNDS
ZIRCONIUM OXIDES