Isotope separation by multiphoton dissociation of molecules using high-power CO/sub 2/ laser radiation. Scaling of the process for carbon isotopes
Data are presented on multiphoton dissociation of halogenated methanes, CF/sub 3/I and CF/sub 3/Br, in a pulsed CO/sub 2/ laser field in the single-pulse irradiation regime. It is shown that the high parameters of an elementary separation event (dissociation yield and selectivity, quantum efficiency) for these molecules can be used to achieve efficient laser separation of the carbon isotopes /sup 12/C and /sup 13/C. An analysis is made of problems involved in organizing the chemical cycle when the process is scaled up. A description is given of an apparatus for scaled-up laser isotope separation, including a pulse-periodic CO/sub 2/ laser with a kilowatt average power, and a laser separation cell. Experiments carried out using this apparatus showed that the high parameters obtained in the single-pulse regime can also be achieved using this design and a yield rate comparable with that of traditional separation systems can be achieved for fairly low energy losses. These results make it possible to develop a commercial system for laser isotope separation using multiphoton dissociation of molecules.
- Research Organization:
- Institute of Spectroscopy, Academy of Sciences of the USSR, Troitsk
- OSTI ID:
- 6875306
- Journal Information:
- Sov. J. Quant. Electron. (Engl. Transl.); (United States), Vol. 12:4
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BROMINATED ALIPHATIC HYDROCARBONS
DISSOCIATION
CARBON ISOTOPES
LASER ISOTOPE SEPARATION
CHLORINATED ALIPHATIC HYDROCARBONS
FLUORINATED ALIPHATIC HYDROCARBONS
MULTI-PHOTON PROCESSES
PULSE TECHNIQUES
QUANTUM EFFICIENCY
EFFICIENCY
HALOGENATED ALIPHATIC HYDROCARBONS
ISOTOPE SEPARATION
ISOTOPES
ORGANIC BROMINE COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
SEPARATION PROCESSES
070100* - Physical Isotope Separation
400303 - Organic Chemistry- Isotope Exchange & Isotope Separation- (-1987)