Synthesis and structural characterization of (PPN)(ClRu/sub 4/(CO)/sub 13/): a butterfly cluster with a bridging chloride
Journal Article
·
· Inorg. Chem.; (United States)
OSTI ID:6874547
The new cluster (PPN)(ClRu/sub 4/(CO)/sub 13/) (PPN = (Ph/sub 3/P)/sub 2/N/sup +/) results from the reaction of Ru/sub 3/(CO)/sub 12/ with (PPN)Cl in refluxing THF. It has been characterized by its spectroscopic properties and by a complete single-crystal X-ray diffraction study. It crystallizes in the space group P anti 1 with Z = 2 and unit cell dimensions a = 14.536 (2) A, b = 16.732 (3) A, c = 11.508 (8) A, ..cap alpha.. = 91.35 (3)/sup 0/, ..beta.. = 93.88 (3)/sup 0/, ..gamma.. = 64.79 (2)/sup 0/, and V = 2527 (2) A. Diffraction data (0/sup 0/ < 2theta less than or equal to 50/sup 0/) were collected with an Enraf-Nonius CAD4 automated diffractometer, using graphite-monochromatized Mo K..cap alpha.. radiation, and the structure was refined to R = 0.061 and R/sub w/ = 0.087 for 5924 independent reflections with I greater than or equal to 3.0 sigma(I). The molecule possesses a butterfly arrangement of the four Ru atoms with the chlorine bridging the two end metals of the open butterfly. Each Ru bears three terminal carbonyls, and one carbonyl ligand bridges the two Ru atoms which constitute the hinge of the butterfly.
- Research Organization:
- Pennsylvania State Univ., University Park
- OSTI ID:
- 6874547
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 19:10; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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Synthesis and X-ray crystal structure of the new nonstoichiometric phase Rb/sub 0. 60/Na/sub 6. 25/Ga/sub 20. 02/
Technical Report
·
Wed Oct 03 00:00:00 EDT 1979
·
OSTI ID:5418849
Preparation and structural characterization of ((Ph/sub 3/P)/sub 2/N)(HFeRu/sub 3/(CO)/sub 13/) and ((Ph/sub 3/P)/sub 2/N)(HFe/sub 2/Ru/sub 2/(CO)/sub 13/)
Journal Article
·
Sat Oct 31 23:00:00 EST 1981
· Inorg. Chem.; (United States)
·
OSTI ID:5949855
Synthesis and X-ray crystal structure of the new nonstoichiometric phase Rb/sub 0. 60/Na/sub 6. 25/Ga/sub 20. 02/
Journal Article
·
Tue Mar 31 23:00:00 EST 1987
· J. Solid State Chem.; (United States)
·
OSTI ID:6634598
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
AROMATICS
BOND ANGLE
BOND LENGTHS
CARBONYLS
CHLORINE COMPOUNDS
COHERENT SCATTERING
COMPLEXES
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DIFFRACTION
DIMENSIONS
FURANS
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
LATTICE PARAMETERS
LENGTH
LIGANDS
MOLECULAR STRUCTURE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
RUTHENIUM COMPLEXES
SCATTERING
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
TETRAHYDROFURAN
TRANSITION ELEMENT COMPLEXES
TRICLINIC LATTICES
X-RAY DIFFRACTION
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
AROMATICS
BOND ANGLE
BOND LENGTHS
CARBONYLS
CHLORINE COMPOUNDS
COHERENT SCATTERING
COMPLEXES
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DIFFRACTION
DIMENSIONS
FURANS
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
LATTICE PARAMETERS
LENGTH
LIGANDS
MOLECULAR STRUCTURE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
RUTHENIUM COMPLEXES
SCATTERING
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
TETRAHYDROFURAN
TRANSITION ELEMENT COMPLEXES
TRICLINIC LATTICES
X-RAY DIFFRACTION