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Influence of redox potential on the anaerobic biotransformation of nitrogen-heterocyclic compounds in anoxic freshwater sediments (revised)

Technical Report ·
OSTI ID:6874096
The potential for degradation of four nitrogen-heterocyclic compounds was investigated in freshwater sediment slurries maintained under denitrifying, sulfate-reducing and methanogenic conditions. Pyridine (10 mg/1) was rapidly transformed within 4 weeks under denitrifying conditions but persisted for up to 3 months under sulfate-reducing and methanogenic conditions. Quinoline (10 mg/1) was completely transformed without a lag phase under methanogenic and sulfate-reducing conditions after incubation for 23 and 45 days, respectively. Under denitrifying conditions, less than 23% of the initial concentration of quinoline was transformed after anaerobic incubation for 83 days. Indole, however, was completely removed from sediment slurries under denitrifying, sulfate-reducing, and methanogenic conditions after anaerobic incubation for 18, 27, and 17 days, respectively. No evidence for biotransformation of carbazole was noted for all anaerobic conditions tested.
Research Organization:
Georgia Univ., Athens, GA (United States)
OSTI ID:
6874096
Report Number(s):
PB-95-136818/XAB; CNN: EPA-R819053
Country of Publication:
United States
Language:
English