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Technology assessment for the determination of chemical agent vapors in demilitarization facilities: Final report

Technical Report ·
DOI:https://doi.org/10.2172/6869952· OSTI ID:6869952

A survey of analytical methods for the determination of chemical agents GB, VX, and HD was made. HD, or mustard, is bis-2-chloroethyl sulfide, and is classified as a blishtering agent. GB, or Sarin, is isopropyl methyl phosphonofluoridate. VX is O-ethyl-S-(2-diisopropylaminoethyl)methylphosphonothioate. Both GB and VX are nerve agents. Included were methods capable of providing for monitoring requirements at the time weighted average (TWA) and allowable stack concentration (ASC) levels in near real time. A review of the currently used automatic continuous air monitoring system (ACAMS) was made as well as a review of the recently developed atmospheric pressure ionization mass spectrometry (APIMS). This report recommends a strategy for research and development for near term and medium term improvement of the overall monitoring program. 12 refs., 1 tab.

Research Organization:
Oak Ridge National Lab., TN (USA)
DOE Contract Number:
AC05-84OR21400
OSTI ID:
6869952
Report Number(s):
ORNL/TM-10346; ON: DE87005265
Country of Publication:
United States
Language:
English