Catalytic properties of rhodium hydridocarbonyl trithienyl-phosphine complexes in the homogeneous hydrogenation and isomerization of unsaturated compounds

Journal Article · Sun Nov 30 23:00:00 EST 1986 · Chem. Heterocycl. Compd. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00575242· OSTI ID:6868286

Dudinov, A A; Bogdanov, B S; Gol'dfalls, Ya L; Kozlova, L M; Litvin, E F

Syntheses are reported for trithienylphosphine analogs of hydridocarbonyltris (triphenylphosphine) rhodium (I) and the catalytic activity of these analogs in the hydrogenation and isomerization of terminal olefins was demonstrated. The PMR chemical shifts and form of the signals of the hydride hydrogen atom of these rhodium hydridocarbonyl complexes correlate with their catalytic properties in homogeneous hydrogenation and isomerization.

• Research Organization: Academy of Sciences of the USSR, Moscow
• OSTI ID: 6868286
• Journal Information: Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Journal Name: Chem. Heterocycl. Compd. (Engl. Transl.); (United States) Vol. 22:6; ISSN CHCCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
CARBONYLS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL COMPOSITION
CHEMICAL REACTIONS
CHEMICAL SHIFT
COMPLEXES
ELECTRON SPIN RESONANCE
ELEMENTS
HOMOGENEOUS CATALYSIS
HYDROCARBONS
HYDROGEN
HYDROGENATION
ISOMERIZATION
MAGNETIC RESONANCE
NONMETALS
ORGANIC COMPOUNDS
PHOSPHINES
PHOSPHORUS COMPOUNDS
RESONANCE
RHODIUM COMPLEXES
TRANSITION ELEMENT COMPLEXES