One-electron transfer equilibria and kinetics of N-methylphenothiazine in micellar systems
Journal Article
·
· J. Phys. Chem.; (United States)
- Univ. di Torino, Italy
The kinetics and equilibria of electron transfer between N-methylphenolthiozine and aquoiron(III) or octacyanomolybdate(V) in the presence of various micellar-forming surfactants (CTAN, Triton, SDS) were investigated by using several spectrophotometric techniques. The presence of micelles strongly influences the equilibria and the kinetics of the reactions. Binding constants are determined and electrostatic and hydrophobic effects in the various micellar systems are analyzed. 8 figures, 5 tables.
- DOE Contract Number:
- W-31109-ENG-38
- OSTI ID:
- 6857024
- Journal Information:
- J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 87; ISSN JPCHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
14 SOLAR ENERGY
140505 -- Solar Energy Conversion-- Photochemical
Photobiological
& Thermochemical Conversion-- (1980-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
AZINES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COMPLEXES
CYANIDES
DATA
ELECTRON TRANSFER
EQUILIBRIUM
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
INFORMATION
IRON COMPLEXES
KINETICS
MICELLAR SYSTEMS
MOLYBDENUM COMPLEXES
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
QUANTITY RATIO
REACTION KINETICS
REDOX REACTIONS
SPECTRA
SURFACTANTS
TRANSITION ELEMENT COMPLEXES
ULTRAVIOLET SPECTRA
140505 -- Solar Energy Conversion-- Photochemical
Photobiological
& Thermochemical Conversion-- (1980-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
AZINES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COMPLEXES
CYANIDES
DATA
ELECTRON TRANSFER
EQUILIBRIUM
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
INFORMATION
IRON COMPLEXES
KINETICS
MICELLAR SYSTEMS
MOLYBDENUM COMPLEXES
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
QUANTITY RATIO
REACTION KINETICS
REDOX REACTIONS
SPECTRA
SURFACTANTS
TRANSITION ELEMENT COMPLEXES
ULTRAVIOLET SPECTRA