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Breathers and photoinduced absorption in polyacetylene

Journal Article · · Phys. Rev. Lett.; (United States)
The dynamics of trans-polyacetylene is studied within the adiabatic model of Su, Schrieffer, and Heeger. A single soliton has a maximum velocity, v/sub m/, which can be higher than the sound velocity. A long-time simulation shows that, from an initial electron-hole pair, a soliton and antisoliton emerge with velocities +- v/sub m/ and that a persistent breather is left behind. This breather may account for the high-energy intragap structure observed in photoinduced absorption, including isotope dependence.
Research Organization:
Center for Nonlinear Studies and Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545
OSTI ID:
6854982
Journal Information:
Phys. Rev. Lett.; (United States), Journal Name: Phys. Rev. Lett.; (United States) Vol. 52:8; ISSN PRLTA
Country of Publication:
United States
Language:
English