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U.S. Department of Energy
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Fundamental research in homogeneous catalysis as related to US energy Problems. Proceedings of a workshop held at Stanford University, Stanford, California on December 4-6, 1974

Technical Report ·
OSTI ID:6845953

Efforts to identify solutions to energy problems by homogeneous catalysis and to recommend areas for fundamental research are reported. Homogeneous catalysts are metal complex catalysts which usually function at milder reaction conditions and often provide greater selectivity than metal or metal-oxide catalysts. A potential research area is the reduction of carbon monoxide with hydrogen over transition metal complexes. Implications of this reaction are discussed for coal gasification, methanation, methanol, the Fischer-Tropsch synthesis, and the synthesis of C2 molecules from C1 molecules. Another important research area is the application of homogeneous catalysis to the conversion of hydrogen, coal, and nitrogen into desirable fuels and chemicals through activation of hydrocarbons, nitrogen, and oxygen. The activation of oxygen for selective oxidation and for fuel cells is described. A section on specific catalysts for individual processes considers the possibility of designing homogeneous catalysis systems to effect specific chemical transformations. Another deals with photochemical energy storage and catalyst activities. Finally, new forms of catalysts are described.

Research Organization:
Stanford Univ., CA (USA). Dept. of Chemistry
OSTI ID:
6845953
Report Number(s):
PB-80-157365
Country of Publication:
United States
Language:
English