Synthesis of yttrium and lanthanide silyloxy complexes from anhydrous nitrate and oxo alkoxide precursors and the x-ray crystal structure of (Ce(OSiPh sub 3 ) sub 3 (THF) sub 3 )(THF)
- Rhone Poulenc, Inc., New Brunswick, NJ (USA)
- Univ. of California, Irvine (USA)
The anhydrous trivalent nitrates (NH{sub 4}){sub x}Ln(NO{sub 3}){sub 3+x} (Ln = Y, Ce, Nd, Pr), prepared by heating Ln(NO{sub 3}){sub 3}(H{sub 2}O){sub y} in the presence of NH{sub 4}NO{sub 3}, react with 3 + x equiv of NaOSiPh{sub 3} in THF to form (Ln(OSiPh{sub 3}){sub 3}(THF){sub 3})(THF) complexes. The crystal structure of the complexes is reported. The anhydrous tetravalent nitrate (NH{sub 4}){sub 2}Ce(NO{sub 3}){sub 6} reacts with 6 equiv of (a) NaOSiPh{sub 3} in DME to form Ce(OSiPh{sub 3}){sub 4}(DME) and (b) NaOSiEt{sub 3} in CH{sub 3}CN to form Ce(OSiEt{sub f3}){sub 4}. (NH{sub 4}){sub 3}Y(NO{sub 3}){sub 6} reacts with NaO{sup i}Pr in 2-propanol to form Y{sub 5}(O{sup i}Pr){sub 13}O, which reacts with Ph{sub 3}SiOH to form (Y(OSiPh{sub 3}){sub 3}(THF){sub 3})(THF). 40 refs., 1 fig., 3 tabs.
- OSTI ID:
- 6835554
- Journal Information:
- Inorganic Chemistry; (USA), Vol. 29:3; ISSN 0020-1669
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AROMATICS
SYNTHESIS
CERIUM COMPLEXES
NEODYMIUM COMPLEXES
PRASEODYMIUM COMPLEXES
SILOXANES
TETRAHYDROFURAN
YTTRIUM COMPLEXES
CRYSTAL STRUCTURE
EXPERIMENTAL DATA
COMPLEXES
DATA
FURANS
HETEROCYCLIC COMPOUNDS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC SILICON COMPOUNDS
RARE EARTH COMPLEXES
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties