ESR spectra of NSO/sub 4//sup 2 -/ in (NH/sub 4/)/sub 2/SO/sub 4/
Journal Article
·
· J. Chem. Phys.; (United States)
OSTI ID:6827975
The slow decay of NH/sub 3//sup +/ and NH/sub 2//sup +/ centers in ammonium sulfate produce a new, very stable, paramagnetic center that has been identified as NSO/sub 4//sup 2 -/. This center has g values of g/sub x/ = 2.012, g/sub y/ = 2.011, and g/sub z/ = 2.007 with the corresponding hfi constants A/sub x/ = A/sub y/ = 0.0 and A/sub z/ = 25.2 G. No change in this center is observed on passage of the crystal through the ferroelectric phase transition.
- Research Organization:
- Univ. of Puerto Rico, Mayaguez
- OSTI ID:
- 6827975
- Journal Information:
- J. Chem. Phys.; (United States), Vol. 74:5
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
AMMONIUM SULFATES
ELECTRON SPIN RESONANCE
RADIOLYSIS
HYPERFINE STRUCTURE
MONOCRYSTALS
RADICALS
X RADIATION
AMMONIUM COMPOUNDS
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTIONS
CHEMISTRY
CRYSTALS
DECOMPOSITION
ELECTROMAGNETIC RADIATION
IONIZING RADIATIONS
MAGNETIC RESONANCE
OXYGEN COMPOUNDS
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIATIONS
RESONANCE
SULFATES
SULFUR COMPOUNDS
400600* - Radiation Chemistry
AMMONIUM SULFATES
ELECTRON SPIN RESONANCE
RADIOLYSIS
HYPERFINE STRUCTURE
MONOCRYSTALS
RADICALS
X RADIATION
AMMONIUM COMPOUNDS
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTIONS
CHEMISTRY
CRYSTALS
DECOMPOSITION
ELECTROMAGNETIC RADIATION
IONIZING RADIATIONS
MAGNETIC RESONANCE
OXYGEN COMPOUNDS
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIATIONS
RESONANCE
SULFATES
SULFUR COMPOUNDS
400600* - Radiation Chemistry