Supported carbon-containing molybdenum and tung sten sulfide catalysts, their preparation and use
Patent
·
OSTI ID:6827774
A supported carbon-containing molybdenum sulfide and tungsten sulfide catalyst useful for conducting methanation and hydrotreating reactions, principally the latter, can be formed by compositing a preselected quantity of a porous, refractory inorganic oxide with a complex salt characterized by the formula B /SUB x/ (MO /SUB y/ S/sub 4/- /SUB y/ ) where B is an organo or hydrocarbyl substituted diammonium ion, an organo or hydrocarbyl substituted ammonium ion or quaternary ammonium ion, or an ionic form of a cyclic amine containing one or more basic N atoms, x is 1 where B is an organo or hydrocarbyl substituted diammonium ion, or 2 where B is an organo or hydrocarbyl substituted ammonium or quaternary ammonium ion or an ionic form of a cyclic amine containing one or more basic N atoms, M is molybdenum or tungsten, and y is 0, or a fraction or whole number ranging up to 3, and heat decomposing the salt of said catalyst precursor composite in the presence of hydrogen sulfide and hydrogen to form said supported carbon-containing molybdenum sulfide or tungsten sulfide catalyst.
- Assignee:
- Exxon Research and Engineering Co.
- Patent Number(s):
- US 4430443
- OSTI ID:
- 6827774
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
02 PETROLEUM
020400 -- Petroleum-- Processing
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
AMINES
AMMONIUM COMPOUNDS
CARBON COMPOUNDS
CATALYST SUPPORTS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL PREPARATION
CHEMICAL REACTIONS
EFFICIENCY
HYDROGENATION
MATERIALS
METHANATION
MOLYBDENUM COMPOUNDS
MOLYBDENUM OXIDES
MOLYBDENUM SULFIDES
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
POROUS MATERIALS
REFRACTORIES
SULFIDES
SULFUR COMPOUNDS
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN COMPOUNDS
TUNGSTEN OXIDES
TUNGSTEN SULFIDES
020400 -- Petroleum-- Processing
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
AMINES
AMMONIUM COMPOUNDS
CARBON COMPOUNDS
CATALYST SUPPORTS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL PREPARATION
CHEMICAL REACTIONS
EFFICIENCY
HYDROGENATION
MATERIALS
METHANATION
MOLYBDENUM COMPOUNDS
MOLYBDENUM OXIDES
MOLYBDENUM SULFIDES
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
POROUS MATERIALS
REFRACTORIES
SULFIDES
SULFUR COMPOUNDS
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN COMPOUNDS
TUNGSTEN OXIDES
TUNGSTEN SULFIDES