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Lignin amine surfactant system followed by sequential polymer slugs

Patent ·
OSTI ID:6818578
A method of recovering hydrocarbons from an underground hydrocarbon formation penetrated by at least one injection well and at least one production well is described which comprises: injecting into the formation through an injection well about 0.05 to about 0.5 pore volumes of an aqueous lignin amine surfactant slug have a concentration of about 0.1% to about 6.0% active component, the lignin amine surfactant slug comprising lignin, a primary amine having about 8 to about 18 carbon atoms and a sulfonate surfactant having an equivalent weight between about 200 and about 400 in the relative concentrations of about 1% to about 20% by weight of amine, about 10% to about 80% by weight of lignin, and about 10% to about 75% by weight of sulfonate surfactant; injecting into the formation about 0.1 to about 0.5 pore volumes of an aqueous buffer slug comprising about 0.01% to about 1.0% of polyacrylamide by weight, less than about 4000 ppm TDS of salinity and less than about 200 ppm of divalent metal ions; injecting into the formation at least 0.2 pore volumes of a relatively high salinity aqueous drive fluid comprising about 0.01% to about 0.5 of polysaccharide by weight; and recovering hydrocarbons and other fluids from the formation through a production well.
Assignee:
Texaco Inc., White Plains, NY
Patent Number(s):
US 4756370
OSTI ID:
6818578
Country of Publication:
United States
Language:
English