Polarized raman spectra of the anthracene-trinitrobenzene complex in the lattice vibrational region
Journal Article
·
· J. Phys. Chem.; (United States)
Polarized Raman spectra of the single crystals of the anthracene - 1,3,5-trinitrobenzene complex and the corresponding complex with deuterium-substituted anthracene were measured in the lattice vibrational region and between 88 K and room temperature. Eleven lattice bands were observed among the 12 bands expected by the symmetry consideration, and each band was assigned to the librational or translational lattice vibrations. This is the first report that gives substantial assignments to the translational lattice vibrations in molecular complexes. Brief discussion is given on the problem of the coupling between the vibrations on the donor and acceptor sublattices.
- Research Organization:
- Gakushuin Univ., Tokyo, Japan
- OSTI ID:
- 6813017
- Journal Information:
- J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 91:3; ISSN JPCHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
01 COAL, LIGNITE, AND PEAT
010600 -- Coal
Lignite
& Peat-- Properties & Composition
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ANTHRACENE
AROMATICS
COMPLEXES
CONDENSED AROMATICS
CRYSTAL STRUCTURE
CRYSTALS
DATA
EXPERIMENTAL DATA
HYDROCARBONS
INFORMATION
LATTICE VIBRATIONS
LOW TEMPERATURE
MEDIUM TEMPERATURE
MONOCRYSTALS
NITRO COMPOUNDS
NITROBENZENE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
RAMAN SPECTRA
SPECTRA
010600 -- Coal
Lignite
& Peat-- Properties & Composition
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ANTHRACENE
AROMATICS
COMPLEXES
CONDENSED AROMATICS
CRYSTAL STRUCTURE
CRYSTALS
DATA
EXPERIMENTAL DATA
HYDROCARBONS
INFORMATION
LATTICE VIBRATIONS
LOW TEMPERATURE
MEDIUM TEMPERATURE
MONOCRYSTALS
NITRO COMPOUNDS
NITROBENZENE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
RAMAN SPECTRA
SPECTRA