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Measurement of retained hydrogen by laser thermal desorption for carbon exposed to sub-eV atomic deuterium

Conference ·
OSTI ID:6809356

Retention levels for sub-eV D/sup 0/ atoms in single crystal and pyrolytic graphite were measured using a newly-developed Laser Thermal Desorption (LTD) technique. Retention levels for single crystals were approx. 3 x 10/sup 13/ D/sup 0//cm/sup 2/ for incident fluences of approx. 10/sup 19/D/sup 0//cm/sup 2/. This is about two orders of magnitude lower than D/sup 0/ retention in pyrolytic graphite, and correlates very well with the differences in effective surface areas. The D(/sup 3/He,p)/sup 4/H/sub e/ Nuclear Reaction Analysis (NRA) was used to confirm retention levels as measured by the LTD technique. A further finding was the influence of a small layer of evaporated tungsten on the sample surface. Such W impurity resulted in an increase of D/sup 0/ retention of up to a factor of ten.

Research Organization:
Toronto Univ., Ontario (Canada). Inst. for Aerospace Studies; Sandia National Labs., Albuquerque, NM (USA)
DOE Contract Number:
AC04-76DP00789
OSTI ID:
6809356
Report Number(s):
SAND-83-2629C; CONF-840520-7; ON: DE84012277
Country of Publication:
United States
Language:
English