Excimer laser photolysis of group 6 metal carbonyls in the gas phase

Journal Article · Thu Mar 22 04:00:00 EST 1990 · Journal of Physical Chemistry; (USA)

DOI:https://doi.org/10.1021/j100369a040· OSTI ID:6807057

Ishikawa, Yoichi; Brown, C E; Hackett, P A; Rayner, D M ^[1]

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1. National Research Council of Canada, Ottawa, Ontario (Canada)

The excimer laser photolysis of Mo(CO){sub 6} in the gas phase has been studied at 351, 308, 248, and 222 nm with laser-based, time-resolved infrared absorption spectroscopy. Results have also been obtained on the 308- and 222-nm photolysis of Cr(CO){sub 6} and on the 222-nm photolysis of W(CO){sub 6}, complementing earlier studies and presenting a complete picture of group 6 metal carbonyl ultraviolet photodecomposition.

• OSTI ID: 6807057
• Journal Information: Journal of Physical Chemistry; (USA), Journal Name: Journal of Physical Chemistry; (USA) Vol. 94:6; ISSN 0022-3654; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
CARBONYLS
CHEMICAL REACTIONS
DATA
DATA ANALYSIS
DECOMPOSITION
ELEMENTS
EXCIMER LASERS
EXPERIMENTAL DATA
GAS ANALYSIS
GAS LASERS
INFORMATION
LASERS
MEASURING INSTRUMENTS
MEASURING METHODS
METALS
MOLYBDENUM
NUMERICAL DATA
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
TRANSITION ELEMENTS