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Characterization and optimization of silicon solar cells

Thesis/Dissertation ·
OSTI ID:6781434
The characteristics of crystalline silicon p-n junction solar cells were studied by numerical modeling of the fundamental semiconductor device equations. This analysis includes all the known physical mechanisms in silicon devices and empirical data of properties of silicon. The limiting mechanisms of silicon solar cells have been quantitatively identified, and the effect of emitter region properties and base doping density on the effect of emitter region properties and base doping density on the performance of solar cells have been analyzed. It is shown that bandgap narrowing and surface recombination are the most important limiting factors. Solar cell efficiencies as a function of base doping density are calculated. The maximum open circuit voltage of silicon solar cells may not exceed 620 mV, while the potential open circuit voltage can reach 680 mV by reducing the surface recombination velocity. The optimum device structure was found systematically by minimizing limiting factors and 18% efficiency cell was realized.
OSTI ID:
6781434
Country of Publication:
United States
Language:
English

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