Mass transfer of volatile organic compounds from drinking water to indoor air: The role of residential dishwashers

Journal Article · Thu Jul 01 04:00:00 EDT 1999 · Environmental Science and Technology

DOI:https://doi.org/10.1021/es981354h· OSTI ID:678066

Howard-Reed, C; Corsi, R L ^[1]; Moya, J ^[2]

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1. Univ. of Texas, Austin, TX (United States). Dept. of Civil Engineering
2. Environmental Protection Agency, Washington, DC (United States)

Contaminated tap water may be a source of volatile organic compounds (VOCs) in residential indoor air. To better understand the extent and impact of chemical emissions from this source, a two-phase mass balance model was developed based on mass transfer kinetics between each phase. Twenty-nine experiments were completed using a residential dishwasher to determine model parameters. During each experiment, inflow water was spiked with a cocktail of chemical tracers with a wide range of physicochemical properties. In each case, the effects of water temperature, detergent, and dish-loading pattern on chemical stripping efficiencies and mass transfer coefficients were determined. Dishwasher headspace ventilation rates were also measured using an isobutylene tracer gas. Chemical stripping efficiencies for a single cycle ranged from 18% to 55% for acetone, from 96% to 98% for toluene, and from 97% to 98% for ethylbenzene and were consistently 100% for cyclohexane. Experimental results indicate that dishwashers have a relatively low but continuous ventilation rate that results in significant chemical storage within the headspace of the dishwasher. In conjunction with relatively high mass transfer coefficients, low ventilation rates generally lead to emissions that are limited by equilibrium conditions after approximately 1--2 min of dishwasher operation.

• OSTI ID: 678066
• Journal Information: Environmental Science and Technology, Journal Name: Environmental Science and Technology Journal Issue: 13 Vol. 33; ISSN ESTHAG; ISSN 0013-936X
• Country of Publication: United States
• Language: English

Related Subjects

54 ENVIRONMENTAL SCIENCES
ACETONE
ALKYLATED AROMATICS
DRINKING WATER
EMISSION
INDOOR AIR POLLUTION
MATHEMATICAL MODELS
POLLUTION SOURCES