Slow chain reactions of Br/sub 2/ and Cl/sub 2/ with HI: Multiple state analysis and vibrational relaxation of HBr(v = 2) and HCl(v = 1--4)

Journal Article · Fri Oct 15 04:00:00 EDT 1982 · J. Chem. Phys.; (United States)

DOI:https://doi.org/10.1063/1.444364· OSTI ID:6773608

Dolson, D A; Leone, S R

Two chain reactions of the general form X+HIk/sub 1/HX(v< or =v/sub max/) +I, I+X/sub 2/k/sub 2/IX+X(X = Br, Cl) are studied by realtime detection of infrared chemiluminescence from the vibrationally excited HX(v) products. Both are characterized by k/sub 2/<

• Research Organization: Joint Institute for Laboratory Astrophysics, University of Colorado and National Bureau of Standards and Department of Chemistry, University of Colorado, Boulder, Colorado 80309
• OSTI ID: 6773608
• Journal Information: J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 77:8; ISSN JCPSA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical &amp; Physicochemical Properties
BROMINE
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMILUMINESCENCE
CHLORINE
ELEMENTS
ENERGY LEVELS
EXCITED STATES
HALOGEN COMPOUNDS
HALOGENS
HYDRIODIC ACID
HYDROBROMIC ACID
HYDROCHLORIC ACID
HYDROGEN COMPOUNDS
INFRARED SPECTRA
INORGANIC ACIDS
IODINE COMPOUNDS
KINETICS
LUMINESCENCE
NONMETALS
REACTION KINETICS
RELAXATION
SPECTRA
VIBRATIONAL STATES