Thermodynamic properties of dichloromethane gas

Journal Article · Wed Oct 01 04:00:00 EDT 1986 · J. Chem. Eng. Data; (United States)

DOI:https://doi.org/10.1021/je00046a022· OSTI ID:6772347

Singh, R P

Virial coefficients, derived from an analysis of precise P-V-T data, form a basis for the determination of thermodynamic properties and the force constants of appropriate intermolecular potential models. An earlier work reports experimental P-V-T measurements for dichloromethane gas from about 350 to 510 K along with compression factors and second virial coefficients. This study presents revised values of second virial coefficients and the following other derived quantities (the figure in parentheses indicates the estimated percent uncertainty): (i) third virial coefficients (2-20); (ii) Stockmayer (12-6-3) force constants; (iii) thermodynamic properties (0.2-0.5 up to 10 atm, increasing to 5 at 30 atm and above); and (iv) fugacity coefficients.

• Research Organization: Dept. of Chemical Engineering, Indian Institute of Technology, Kanpur 208 016
• OSTI ID: 6772347
• Journal Information: J. Chem. Eng. Data; (United States), Journal Name: J. Chem. Eng. Data; (United States) Vol. 31:4; ISSN JCEAA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
COMPRESSION
DATA ANALYSIS
DATA COVARIANCES
HIGH TEMPERATURE
MATHEMATICAL MODELS
MEDIUM PRESSURE
MEDIUM TEMPERATURE
METHYLENE CHLORIDE
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PHYSICAL PROPERTIES
PRESSURE MEASUREMENT
TEMPERATURE MEASUREMENT
THERMODYNAMIC PROPERTIES
VOLUME