Surface science study of selective ethylene epoxidation catalyzed by the Ag(110) surface: Structural sensitivity

Journal Article · Sun Apr 01 04:00:00 EST 1984 · J. Vac. Sci. Technol., A; (United States)

DOI:https://doi.org/10.1116/1.572665· OSTI ID:6753564

Campbell, C T

The selective oxidation of ethylene to ethylene epoxide (C/sub 2/H/sub 4/+1/2O/sub 2/..-->..C/sub 2/H/sub 4/O) over Ag is the simplest example of kinetically controlled, selective heterogeneous catalysis. We have studied the steady-state kinetics and selectivity of this reaction for the first time on a clean, well-characterized Ag(110) surface by using a special apparatus which allows rapid (approx.20 s) transfer between a high-pressure catalytic microreactor and an ultrahigh vacuum surface analysis (AES, XPS, LEED, TDS) chamber. The effects of temperature and reactant pressures upon the rate and selectivity are virtually identical on Ag(110) and supported, high surface area Ag catalysts. The absolute specific rate (per Ag surface atom) is, however, some 100-fold higher for Ag(110) than for high surface area catalysts. This is related to the well-known structural sensitivity of this reaction. It is postulated that a small percentage of (110) planes (or (110)-like sites) are responsible for most of the catalytic activity of high surface area catalysts. The high activity of the (110) plane is attributed to its high sticking probability for dissociative oxygen adsorption, since the rate of ethylene epoxidation is shown in a related work (Ref. 1: C. T. Campbell and M. T. Paffett, Surf. Sci. (in press)) to be proportional to the coverage of atomically adsorbed oxygen at constant temperature and ethylene pressure.

• Research Organization: Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545
• OSTI ID: 6753564
• Journal Information: J. Vac. Sci. Technol., A; (United States), Journal Name: J. Vac. Sci. Technol., A; (United States) Vol. 2:2; ISSN JVTAD
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKENES
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
ELEMENTS
EPOXIDES
ETHYLENE
HYDROCARBONS
KINETICS
METALS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDATION
REACTION KINETICS
SILVER
TRANSITION ELEMENTS
ULTRAHIGH VACUUM
YIELDS