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Title: Three-dimensional shock-change relations for reactive fluids

Technical Report ·
DOI:https://doi.org/10.2172/6752317· OSTI ID:6752317

The equations of motion governing reactive fluid flow, together with the Rankine--Hugoniot jump conditions and thermodynamic considerations, are used to develop one- and three-dimensional shock-change relations for shock waves propagating in reactive fluids. The relations are derived in Cartesian space coordinates, for a uniform, motionless state ahead of the shock. In three dimensions, parameterization of the shock surface in terms of two independent curvilinear surface coordinates and the use of some results from the theory of surfaces are required, but the shock-change relation obtained depends on the surface configuration only through the mean curvature. One form of shock-change relation, both in three dimensions and in its one-dimensional specialization, is developed without recourse to the jump conditions. These conditions and thermodynamic considerations are then used to cast the relations in terms of different state variables and to show the relative effects on the shock change of reaction in, and immediately behind, the shock front. Simplifications are indicated for evaluating thermodynamic derivatives and applying shock-change relations with common equation-of-state assumptions.

Research Organization:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
DOE Contract Number:
W-7405-ENG-36
OSTI ID:
6752317
Report Number(s):
LA-7253
Country of Publication:
United States
Language:
English