Chemical storage of light energy
Technical Report
·
OSTI ID:6743125
The objective is to develop new 2,2'-bipyridinyl ligands with long-chain, electron donating substituents in the 4,4'-positions and study their complexation with ruthenium for ultimate use as catalysts in the generation of hydrogen by photoreduction of water. Initial development focused on new, practical syntheses of 2,2'-bipyridinyl derivatives. Accomplishments include the synthesis and characterization of 2,2'-bipyridinyl containing 4,4'-bis (ethylthio) substituents, 4,4'-bis(tetradecanamido) substituents, and 4,4'-bis(tetradecylamino) substituents.
- Research Organization:
- Rensselaer Polytechnic Inst., Troy, NY (USA)
- DOE Contract Number:
- AC02-77CH00178
- OSTI ID:
- 6743125
- Report Number(s):
- SERI/STR-231-1722; ON: DE82022156
- Country of Publication:
- United States
- Language:
- English
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Journal Article
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Thu Dec 12 23:00:00 EST 1985
· J. Org. Chem.; (United States)
·
OSTI ID:5814849
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Fri Nov 02 00:00:00 EDT 2018
· Advanced Synthesis & Catalysis (ACS)
·
OSTI ID:1489353
Related Subjects
08 HYDROGEN
080106* -- Hydrogen-- Production-- Biosynthesis & Photochemical Processes
14 SOLAR ENERGY
140505 -- Solar Energy Conversion-- Photochemical
Photobiological
& Thermochemical Conversion-- (1980-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
AZINES
BIPYRIDINES
CATALYTIC EFFECTS
CHEMICAL REACTIONS
COMPLEXES
DECOMPOSITION
ENERGY STORAGE
HETEROCYCLIC COMPOUNDS
HYDROGEN PRODUCTION
LIGANDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHOTOCHEMICAL ENERGY STORAGE
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
PYRIDINES
RUTHENIUM COMPLEXES
STORAGE
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
080106* -- Hydrogen-- Production-- Biosynthesis & Photochemical Processes
14 SOLAR ENERGY
140505 -- Solar Energy Conversion-- Photochemical
Photobiological
& Thermochemical Conversion-- (1980-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
AZINES
BIPYRIDINES
CATALYTIC EFFECTS
CHEMICAL REACTIONS
COMPLEXES
DECOMPOSITION
ENERGY STORAGE
HETEROCYCLIC COMPOUNDS
HYDROGEN PRODUCTION
LIGANDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHOTOCHEMICAL ENERGY STORAGE
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
PYRIDINES
RUTHENIUM COMPLEXES
STORAGE
SYNTHESIS
TRANSITION ELEMENT COMPLEXES