Visible and near IR Si--H vibrational overtones in SiH/sub 4/

Journal Article · Fri Jun 15 00:00:00 EDT 1984 · J. Chem. Phys.; (United States)

OSTI ID:6741774

Bernheim, R A; Lampe, F W; O'Keefe, J F; Qualey, III, J R

Absorption spectra in the 12 000 to 18 000 cm/sup -1/ range have been recorded for gaseous SiH/sub 4/ using intracavity photoacoustic detection with cw dye lasers. The observed transitions correspond to the ..delta..v = 6--9 overtones of the Si--H local mode stretch and show considerable rotational structure.

• Research Organization: Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802
• OSTI ID: 6741774
• Journal Information: J. Chem. Phys.; (United States), Vol. 80:12
• Country of Publication: United States
• Language: English

Related Subjects

74 ATOMIC AND MOLECULAR PHYSICS
SILANES
INFRARED SPECTRA
VISIBLE SPECTRA
ABSORPTION SPECTRA
ENERGY-LEVEL TRANSITIONS
VIBRATIONAL STATES
ENERGY LEVELS
EXCITED STATES
HYDRIDES
HYDROGEN COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC SILICON COMPOUNDS
SILICON COMPOUNDS
SPECTRA
640302* - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory