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Dynamic intersystem crossing in solid bis(phenanthroline)bis(cyanotrihydroborato)iron(II)

Conference · · Inorg. Chem.; (United States)
OSTI ID:6729787
Variable-temperature Moessbauer, magnetic susceptibility, and infrared studies of Fe(phen)/sub 2/(NCBH/sub 3/)/sub 2/ reveal the occurrence of a reversible, gradual singlet/quintet intersystem crossing above room temperature. Moessbauer spectra of the complex in the transition region are interpreted as showing the occurrence of a novel (for Fe(II)), fast singlet/quintet interconversion. 24 references, 5 figures, 3 tables.
Research Organization:
Kansas State Univ., Manhattan
DOE Contract Number:
AC02-76ER02753
OSTI ID:
6729787
Conference Information:
Journal Name: Inorg. Chem.; (United States) Journal Volume: 23:17
Country of Publication:
United States
Language:
English