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Uranium and thorium series isotopes as indicators of geochemical processes in recent Venezuela Basin sediments

Thesis/Dissertation ·
OSTI ID:6721056

Several uranium and thorium series isotopes are important indicators of abyssal geochemical and physical processes: sedimentation, bioturbation, compaction, dissolution and precipitation. This research was designed to investigate the relative importance of each of these on early sediment diagenesis in different abyssal environments. Sediment samples were collected from three different sedimentary environments from the Venezuela Basin. Samples were designated as pelagic carbonate, hemipelagic and turbidite-rich, based on bulk sediment characteristics. Selected members of the U and Th radioisotope series ({sup 238}U, {sup 234}U, {sup 230}Th, {sup 226}Ra, {sup 210}Pb, and {sup 232}Th), {sup 14}C, and anthropogenic {sup 239,240}Pu were determined on selected intervals. Other sedimentary parameters, including porosity, calcium carbonate content, stable isotopes, macrofaunal abundances, organic carbon and grain size, were measured or available from the literature. A model, based on the constancy of {sup 230}Th production in sea water, was developed to determine fine-scale sedimentation rates for the last 14 ky, 6 ky, and 2 ky for sediments from pelagic carbonate, hemipelagic and turbidite-rich environments, respectively. Nannofossil {delta}{sup 13}C values correlated well with carbonate accumulation rates. {sup 226}Ra fluxes across the sediment/sea water interface were estimated from losses in the expected {sup 226}Ra activities. {sup 226}Ra fluxes across the interface were low due to low {sup 230}Th activities. A multi-layer explicit finite difference model was developed to simulate the effects of diffusive and advective bioturbation on the distributions of {sup 210}Pb and {sup 239,240}Pu in abyssal sediments.

Research Organization:
Texas A and M Univ., College Station, TX (USA)
OSTI ID:
6721056
Country of Publication:
United States
Language:
English

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