Temperature effects on the performance of PMAN-derived carbon anodes in 1M LiPF{sub 6}/EC-DMC solution
The effect of temperature on the reversible and irreversible capacities of disordered carbons derived from polymethacryonitrile (PMAN) and divinylbenzene (DVB) copolymers was studied in 1 M LiPF{sub 6}/ethylene carbonate (EC)-dimethyl carbonate (DMC) (1:1 v/v) solution by galvanostatic cycling. The kinetics of passive film formation were examined by complex-impedance spectroscopy. Temperatures of 5, 21, and 35 C were used in the study.
- Research Organization:
- Sandia National Labs., Albuquerque, NM (United States)
- Sponsoring Organization:
- USDOE Office of Financial Management and Controller, Washington, DC (United States)
- DOE Contract Number:
- AC04-94AL85000
- OSTI ID:
- 672103
- Report Number(s):
- SAND--98-0939C; CONF-980644--; ON: DE98004742; BR: YN0100000
- Country of Publication:
- United States
- Language:
- English
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