Synthesis and characterization of III-V semiconductor clusters: GaP in zeolite Y

Journal Article · Sun Nov 26 23:00:00 EST 1989 · Journal of the American Chemical Society; (USA)

DOI:https://doi.org/10.1021/ja00202a047· OSTI ID:6719909

MacDougall, J E; Eckert, H; Stucky, G D ^[1]; Herron, N; Wang, Y ^[2]; Moller, K; Bein, T ^[3]; Cox, D ^[4]

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1. Univ. of California, Santa Barbara (USA)
2. E.I. du Pont de Nemours Co., Inc., Wilmington, DE (USA)
3. Univ. of New Mexico, Albuquerque (USA)
4. Brookhaven National Labs., Upton, NY (USA)

Size quantization effects observed in small semiconductor clusters are currently of great interest for potential nonlinear optic and photocatalytic applications. While materials based on II-VI semiconductors have been extensively studied, the preparation of III-V size quantized semiconductors has been hampered by the much less-developed solution state chemistry in such systems. With the use of inclusion chemistry, we have succeeded in preparing small clusters of GaP in a crystalline, periodic environment of well-defined size and shape (zeolite Y).

• OSTI ID: 6719909
• Journal Information: Journal of the American Chemical Society; (USA), Journal Name: Journal of the American Chemical Society; (USA) Vol. 111:20; ISSN 0002-7863; ISSN JACSA
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360601* -- Other Materials-- Preparation & Manufacture
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400200 -- Inorganic
Organic
& Physical Chemistry
400500 -- Photochemistry
CALCULATION METHODS
DATA
DATA ANALYSIS
EXPERIMENTAL DATA
GALLIUM COMPOUNDS
GALLIUM PHOSPHIDES
INFORMATION
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
MATERIALS
MEASURING INSTRUMENTS
MEASURING METHODS
MINERALS
NUMERICAL DATA
OPTICAL PROPERTIES
PHOSPHIDES
PHOSPHORUS COMPOUNDS
PHYSICAL PROPERTIES
PNICTIDES
SEMICONDUCTOR MATERIALS
SYNTHESIS
ZEOLITES