A kinetic and thermodynamic study of the reversible C-H insertion/elimination of alkanes at iridium
Technical Report
·
OSTI ID:6713660
The following areas of research are reported: kinetics of the thermolysis of a hydridocyclohexyliridium(III) complex Cp(PMe/sub 3/)Ir(Cy)(H) (where Cp = n/sup 5/-C/sub 5/Me/sub 5/ and Cy = cyclohexyl) in benzene: the mechanism of thermal C-H insertion/elimination; an equilibrium study of reversible alkane C-H insertion/elimination; the synthesis of (n/sup 5/-cyclopentadienyl)-(trimethylphosphine)dihydridoiridium(III) and its use in the preparation of hydridoaryl and hydridoalkyl complexes.
- Research Organization:
- California Univ., Berkeley (USA)
- DOE Contract Number:
- AC03-76SF00098
- OSTI ID:
- 6713660
- Report Number(s):
- LBL-22534; ON: DE87004599
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
ALKANES
AROMATICS
BENZENE
CHEMICAL PREPARATION
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CYCLOALKANES
CYCLOHEXANE
DEUTERIUM
HYDROCARBONS
HYDROGEN ISOTOPES
IRIDIUM COMPOUNDS
ISOTOPE EFFECTS
ISOTOPES
KINETICS
LIGHT NUCLEI
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
SOLVENT PROPERTIES
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
ALKANES
AROMATICS
BENZENE
CHEMICAL PREPARATION
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CYCLOALKANES
CYCLOHEXANE
DEUTERIUM
HYDROCARBONS
HYDROGEN ISOTOPES
IRIDIUM COMPOUNDS
ISOTOPE EFFECTS
ISOTOPES
KINETICS
LIGHT NUCLEI
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
SOLVENT PROPERTIES
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS