Chemistry and thermodynamics of ruthenium and some of its inorganic compounds and aqueous species

Journal Article · Fri Feb 01 04:00:00 EST 1985 · Chem. Rev.; (United States)

DOI:https://doi.org/10.1021/cr00065a001· OSTI ID:6713004

Rard, J A

Chemical and thermodynamic data for ruthenium and many of its inorganic compounds and aqueous solutions have been critically reviewed. Values for thermodynamic properties are recommended when both the chemistry and thermodynamics are sufficiently well characterized to warrant confidence in them. Systems reviewed included metallic Ru, phase diagrams with metals and non-metals, chalcogenides, oxides, halides, oxyhalides, oxysulfur, and oxynitrogen compounds. Aqueous systems considered are aquo ions, hydrolyzed cations, oxyanions, halide complexes, and sulfate complexes. The oxide, halide, oxyhalide, and aqueous systems (both noncomplexing and complexing media) are described in considerable detail because of their great complexity and because of conflicting claims and questionable analyses in some published reports. Recommendations are made for data that need to be measured or remeasured. 480 references, 1 figure, 9 tables.

• Research Organization: Lawrence Livermore National Lab., CA
• DOE Contract Number: W-7405-ENG-48
• OSTI ID: 6713004
• Journal Information: Chem. Rev.; (United States), Journal Name: Chem. Rev.; (United States) Vol. 85:1; ISSN CHREA
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360104 -- Metals & Alloys-- Physical Properties
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AQUEOUS SOLUTIONS
CHEMICAL PROPERTIES
DATA
DATA COMPILATION
DISPERSIONS
DOCUMENT TYPES
ELEMENTS
INFORMATION
METALS
MIXTURES
PHYSICAL PROPERTIES
PLATINUM METALS
REFRACTORY METAL COMPOUNDS
REVIEWS
RUTHENIUM
RUTHENIUM COMPOUNDS
SOLUTIONS
THERMODYNAMIC PROPERTIES
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS