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Title: Glassy phase and reaction products of Iowa fly ashes

Thesis/Dissertation ·
OSTI ID:6706205

The crystalline and glassy phases of a series of low calcium to high calcium Iowa fly ashes were investigated. Elemental analyses were conducted by quantitative x-ray fluorescence (QXRF) techniques. Crystalline compounds were determined by quantitative x-ray diffraction (QXRD). Glassy phase compositions of the ashes were estimated from these data. The glassy phase of the high calcium ashes is believed to be in a more highly strained chemical state as compared to the low calcium ashes, and hence, more reactive. It was shown that the elemental analysis consistency of Iowa ashes, from a given generating station, is not a valid indicator of its fundamental physical properties. The glassy phase of Iowa fly ashes are shown to contain significant amounts of the cementitious building blocks of calcium, aluminum, and silicon.

Research Organization:
Iowa State Univ. of Science and Technology, Ames (USA)
OSTI ID:
6706205
Resource Relation:
Other Information: Thesis (Ph. D.)
Country of Publication:
United States
Language:
English