Complexation of some transition metls, rare earth elements, and thorium with a poly(dithiocarbamate) chelating resin

Journal Article · Sun Feb 01 04:00:00 EST 1981 · Anal. Chem.; (United States)

DOI:https://doi.org/10.1021/ac00225a040· OSTI ID:6699519

Miyazaki, A; Barnes, R M

Complexation properties of a poly(dithiocarbamate) resin for Fe(III), Fe(II), Cr(VI), Cr(III), V(V), V(IV), T(IV), Mo(VI), W(VI), Th(IV), 14 rare earth elements, and Os are examined by inductively coupled plasma-atomic emission spectrometry (ICP-AES). Fe(III) and Cr(VI) complex with the resin, whereas Fe(II) and Cr(III) do not. Considerable differences in uptake also exist between V(V) and V(IV) and Ce(III) and Ce(IV). The digestion of the resin with nitric acid followed by dilution with (3 + 1) nitric acid-water is suitable for inductively coupled plasma-atomic emission spectrometry except for W.

• Research Organization: Univ. of Massachusetts, Amherst
• DOE Contract Number: AC02-77EV04320
• OSTI ID: 6699519
• Journal Information: Anal. Chem.; (United States), Journal Name: Anal. Chem.; (United States) Vol. 53:2; ISSN ANCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400104 -- Spectral Procedures-- (-1987)
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ACTINIDE COMPLEXES
CARBAMATES
CARBONIC ACID DERIVATIVES
CARBOXYLIC ACID SALTS
CERIUM COMPLEXES
CHEMICAL PREPARATION
CHEMICAL REACTIONS
CHROMIUM COMPLEXES
COMPLEXES
DYSPROSIUM COMPLEXES
EMISSION SPECTROSCOPY
ERBIUM COMPLEXES
EUROPIUM COMPLEXES
GADOLINIUM COMPLEXES
HOLMIUM COMPLEXES
IRON COMPLEXES
LANTHANUM COMPLEXES
LUTETIUM COMPLEXES
MOLYBDENUM COMPLEXES
NEODYMIUM COMPLEXES
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC POLYMERS
ORGANIC SULFUR COMPOUNDS
OSMIUM COMPLEXES
PETROCHEMICALS
PETROLEUM PRODUCTS
PH VALUE
POLYMERS
PRASEODYMIUM COMPLEXES
RARE EARTH COMPLEXES
RESINS
SAMARIUM COMPLEXES
SPECTROSCOPY
SYNTHESIS
TERBIUM COMPLEXES
THORIUM COMPLEXES
TITANIUM COMPLEXES
TRANSITION ELEMENT COMPLEXES
TUNGSTEN COMPLEXES
VANADIUM COMPLEXES
YTTERBIUM COMPLEXES