Direct observation of the protonation of acetone ketyl radical by conductometric pulse radiolysis. [8-MeV electrons]
Journal Article
·
· J. Phys. Chem.; (United States)
Improvements in conductometric pulse radiolysis methods allow direct observation of the protonation of the acetone ketyl radical anion on the 10-ns time scale. The protonation period of 9.7 +- 0.5 ns determined here is in good agreement with that estimated from the ESR line broadening studies of Laroff and Fessenden, (J. Phys. Chem., 77, 1283(1973)).
- Research Organization:
- Univ. of Notre Dame, IN
- OSTI ID:
- 6698733
- Journal Information:
- J. Phys. Chem.; (United States), Vol. 84:25
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
ACETONE
RADIOLYSIS
AQUEOUS SOLUTIONS
COMPARATIVE EVALUATIONS
ELECTRIC CONDUCTIVITY
ELECTRON BEAMS
ELECTRON SPIN RESONANCE
HYDRATION
MEV RANGE 01-10
PULSED IRRADIATION
RADICALS
SOLVATED ELECTRONS
BEAMS
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTIONS
CHEMISTRY
DECOMPOSITION
DISPERSIONS
ELECTRICAL PROPERTIES
ELECTRONS
ELEMENTARY PARTICLES
ENERGY RANGE
FERMIONS
IRRADIATION
KETONES
LEPTON BEAMS
LEPTONS
MAGNETIC RESONANCE
MEV RANGE
MIXTURES
ORGANIC COMPOUNDS
PARTICLE BEAMS
PHYSICAL PROPERTIES
RADIATION CHEMISTRY
RADIATION EFFECTS
RESONANCE
SOLUTIONS
SOLVATION
400600* - Radiation Chemistry
ACETONE
RADIOLYSIS
AQUEOUS SOLUTIONS
COMPARATIVE EVALUATIONS
ELECTRIC CONDUCTIVITY
ELECTRON BEAMS
ELECTRON SPIN RESONANCE
HYDRATION
MEV RANGE 01-10
PULSED IRRADIATION
RADICALS
SOLVATED ELECTRONS
BEAMS
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTIONS
CHEMISTRY
DECOMPOSITION
DISPERSIONS
ELECTRICAL PROPERTIES
ELECTRONS
ELEMENTARY PARTICLES
ENERGY RANGE
FERMIONS
IRRADIATION
KETONES
LEPTON BEAMS
LEPTONS
MAGNETIC RESONANCE
MEV RANGE
MIXTURES
ORGANIC COMPOUNDS
PARTICLE BEAMS
PHYSICAL PROPERTIES
RADIATION CHEMISTRY
RADIATION EFFECTS
RESONANCE
SOLUTIONS
SOLVATION
400600* - Radiation Chemistry